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  • 21-11-2017
  • Chemistry
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Which of these expressions correctly expresses the solubility-product constant for ag3po4 in water?

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W0lf93
W0lf93 W0lf93
  • 30-11-2017
[Ag+]3[PO4]3- Ag3PO4(aq) ----> 3Ag^+(aq) + PO4^3-(aq) In pure water, the molarity of PO4^3-, which is 1.76x10^-5 M, also represents the molar solubility of Ag3PO4, that means that max 1.76x10^-5 mol Ag3PO4 dissolves in 1L (1000 mL) of water. When the amount of water is halved to 500 mL, the solubility of Ag3PO4 is also halved. (8.8x10^-5 mol). Ag3PO4(aq) ----> 3Ag^+(aq) + PO4^3-(aq) 8.8x10^-5 mol ..... 3x8.8x10^-5 mol = 2.64x10^-4 mol [Ag^+] = n / V = 2.64x10^-4 mol / 0.500 L = 5.28x10^-4 M
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